As for RPN, it's one of those things I didn't get until I was in my 30s and started using it. Then used it more. And now I'm at the point where using a "normal" calculator is a frustrating experience. I got very used to the stack and having intermediate results. I find it highly frustrating that the windows calculator still doesn't have it as an option, and that when asked about it the developers seemed confused why anyone would want it.
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PCalc is indeed excellent.
As for RPN, it's one of those things I didn't get until I was in my 30s and started using it. Then used it more. And now I'm at the point where using a "normal" calculator is a frustrating experience. I got very used to the stack and having intermediate results. I find it highly frustrating that the windows calculator still doesn't have it as an option, and that when asked about it the developers seemed confused why anyone would want it.
Free42 has filled the gap though.