Trying to replace ACH has quite a few interesting elements that you must solve.
A decent ACH must offer guarantees that payments are final and will be settled - even if the sending customer was banking with Lehman Bros, and the payment was received the day Lehman went down. Otherwise your system would go bankrupt with the first financial crisis; and since it's obvious, then no bank would use your ACH.
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Trying to replace ACH has quite a few interesting elements that you must solve. A decent ACH must offer guarantees that payments are final and will be settled - even if the sending customer was banking with Lehman Bros, and the payment was received the day Lehman went down. Otherwise your system would go bankrupt with the first financial crisis; and since it's obvious, then no bank would use your ACH.