I think the GP meant that you wouldn't normally want to try to use an ADC for digital communication because the general-purpose ADCs in, e.g. microcontrollers are either overkill (10 bits just to detect a level!?) or too slow (max sampling rate) to do high-performance I/O. You'd be better off using an existing protocol with just two voltage levels and the GPIO pins. You can make an analog circuit to transform the two voltage levels you do have into the (typically 0-5V) levels detected by the GPIO on the microcontroller.
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I think the GP meant that you wouldn't normally want to try to use an ADC for digital communication because the general-purpose ADCs in, e.g. microcontrollers are either overkill (10 bits just to detect a level!?) or too slow (max sampling rate) to do high-performance I/O. You'd be better off using an existing protocol with just two voltage levels and the GPIO pins. You can make an analog circuit to transform the two voltage levels you do have into the (typically 0-5V) levels detected by the GPIO on the microcontroller.